Lamb shift

In physics, the Lamb shift, named after Willis Lamb, is an anomalous difference in energy between two electron orbitals in a hydrogen atom. The difference was not predicted by theory and it cannot be derived from the Dirac equation, which predicts identical energies. Hence the Lamb shift is a deviation from theory seen in the differing energies contained by the 2S1/2 and 2P1/2 orbitals of the hydrogen atom.